The Romans’ self-healing concrete

One of the secrets to the success of Rome: self-healing concrete:

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Now, an international team has discovered ancient concrete-manufacturing techniques that incorporated several key “self-healing” properties. For years, researchers believed the key to the ancient concrete’s durability was one ingredient: pozzolanic material, such as volcanic ash from the area of Pozzuoli, on the Bay of Naples…

Historians say this specific kind of ash was shipped all across the Roman empire for use in construction projects, being described as a key ingredient for concrete at the time. After closer examination, these ancient samples also contain small, distinctive, millimeter-scale bright white mineral features. They were common component of Roman concretes. The white chunks — often called “lime clasts” — come from lime, another key ingredient in ancient concrete mix.

Masic adds that, during the hot mixing process, lime clasts develop a characteristically brittle nanoparticulate architecture. This creates an easily fractured and reactive calcium source, which could provide a “critical” self-healing ability for building materials. As soon as tiny cracks start to form within the concrete, they can preferentially travel through the high-surface-area lime clasts.

Prof. Masic explains that the material can then react with water, creating a calcium-saturated solution. It then recrystallizes as calcium carbonate and quickly fills the crack, or reacts with pozzolanic materials to further strengthen the material.

What I often wonder about inventions and techniques of the ancient world is how exactly they came about. How did Romans discover that a particular component – pozzolanic material – made concrete better in the long-term? I would guess there is evidence to suggest when this emerged and how it was dispersed but we may not know exactly how this formula developed.

If this could be incorporated into modern materials, could this make concrete even more important? I remember reading about the importance of concrete in How the World Really Works. Could this mean roads that do not need to be repaired as often, buildings that last longer, and numerous other applications?

This is also a reminder that infrastructure mattered for ancient empires and continues to matter today for modern everyday life. Even small improvements to basic materials or processes could have a tremendous effect given the scale and speed of today’s world.

Beyond technological advances: “50 Social Innovations that Changed the World”

After reading The Atlantic‘s recent list of the 50 greatest inventions, one reader sends in a list of the most important social innovations. Here is the top 10 – in chronological order:

50 Social innovations that changed the world more or less in chronological order.  Rank order in top 10 shown in [ ]

1. Irrigation that
2. created a structured bureaucracy, land measurement and administration in Egypt and Mesopotamia
3. mathematics [3]
4. creation of nations as workable structures
5. empires based  on bureaucracy and military discipline
6. writing, instructions could be sent over distance – Incas used knots [1]
7. written rules and laws – the lawyers and courts as independent
8. alphabet [11]
9. agriculture and and animal husbandry skills that could be recorder and spread
10. history as peoples myths and lessons…

One could argue that these social skills made other technologies possible. It provided a social infrastructure. Imagine trying to large social groups without bureaucracy. While it often gets a bad name today, you couldn’t have the Roman army or city-states or the modern welfare state without bureaucracy.

I’m a little surprised that language isn’t included here – writing makes it but perhaps language predates the beginning of this list. It is also intriguing that economics and political science make the end of the list – perhaps this betrays the opinions of the author but few other academic disciplines make the list.